Saturday, June 9, 2018

inorganic chemistry - Colour intensity of transition metal complexes


Even though they are both $\mathrm{d^7}$ complexes, the colour of $\ce{[Co(H2O)6]^2+}$ is pale whereas that of $\ce{[CoCl4]^2-}$ is more intense. Does the octahedral or tetrahedral geometry matter in determining the molar absorption coefficient of the two species?




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...