organic chemistry - Which platonic solids have been built as carbon skeletons?

There are 5 platonic solids: the tetrahedron, the octahedron, the cube, the dodecahedron and the icosahedron.

How many of these have been realised as carbon skeletons by chemical synthesis?

Answer

The previous answer and comments have already listed out the known platonic hydrocarbons, however, since the OP had expressed an interest in the synthesis of these platonic hydrocarbons in one of his comments, I have provided some commentary to that effect along with links to the original papers that first reported these compounds. Also, of interest would be this paper

Tetrahedrane

Technically speaking, Tetrahedrane ($\ce{C4H4}$) still remains a hypothetical compound, as an unsubstituted version hasn't been synthesised yet.

Two stable derivatives, whose synthesis has been achieved include tetra-tert-butyltetrahedrane (prepared in 1978 by Günther Maier) and tetra(trimethylsilyl)tetrahedrane (reported in 2002).

Tetra-tert-butyltetrahedrane

The original paper discussing the synthesis can be found here. The synthesis has been summarised below. The authors rationalise the stability of this compound as follows:

If all the corners of the tetrahedrane unit are occupied by bulky groups then on lengthening one bond of the ring skeleton , two tert-butyl groups tending to increase their mutual separation will be forced back together by the other ones ("corset effect"); a tetrahedral structure permits the four substituents to adopt a regular spherical distribution and hence a maximum mutual separation.

In simpler terms, trying to break a bond forces the bulky substituents together increasing strain.

Tetrakis(trimethylsilyl)tetrahedrane

Again, the synthetic route is given below. The original paper is also by Günther Maier.

Reaction with methyllithium has yielded the stable tetrahedranyllithium derivative. These coupling reactions with this lithium compound have allowed access to more derivatives, for example the dimer in the last step of the reaction scheme given above.

This compound is far more stable than the tert-butyl analogue. On account of the silicon–carbon bond being longer than a carbon–carbon bond, the corset effect is reduced. $\sigma$-donor character of the trimethylsilyl explains the increased stabilisation of the tetrahedrane.

The tetrahedrane skeleton is made up of banana bonds, and hence the carbon atoms are high in s-orbital character

Cubane

Cubane was first synthetically realised by Eaton and Cole in 1964. The synthetic scheme from the original paper is given below:

Note: In the original synthesis, the starting material for this, 2-bromocyclopentadienone, was obtained from 2-cyclopentenone via allylic bromination with N-bromosuccinimide in carbon tetrachloride followed by addition of molecular bromine to the alkene gives a 2,3,4-tribromocyclopentanone. After treatment of this compound with diethylamine in diethyl ether, which causes elimination of two equivalents of hydrogen bromide, we get the desired diene product.

Again, the cubane is kinetically stable because of lack of readily accessible decomposition paths.

Dodecahedrane

Dodecahedrane was synthesised by Leo Paquette in 1982, and later by Prinzbach (via pagodane) in 1987.

The pagodane synthetic route has been given below.

Paquette's 1982 organic synthesis takes about 29 steps, and starts from cyclopentadiene, and for the sake of brevity, I have not presented it here.