Sunday, May 20, 2018

ions - Superscript and subscript together after the same atom



In the chemical formula of some ion compounds, there is the necessity to write the charge in the superscript and the numbers of atoms in the subscript, but together at the right of the same symbol like in the PO43- ion:


stacked vs. staggered notation for the phosphate anion


Does IUPAC provide universal guidelines saying that I have to typewrite the two numbers in a stacked or staggered way?



Answer



From IUPAC Green Book [1, p. 51]:



In writing the formula for a complex ion, spacing for charge number can be added (staggered arrangement), as well as parentheses: $\ce{SO4^2-}$, $\ce{(SO4)^2-}$. The staggered arrangement is now recommended.



Also, as you are apparently a $\mathrm{\LaTeX}$-user, the same convention is used by default in chemformula package. From the manual:




If a compound does not start with a sub- or superscript and there is both a sub- and a superscript, the superscript is shifted additionally by a length determined from the option charge-hshift = {❬dim❭}, also see page 13f.


The second point follows IUPAC’s recommendations.



References:



  1. IUPAC “Green Book” Quantities, Units, and Symbols in Physical Chemistry, 3rd ed.; Cohen, R. E., Mills, I., Eds.; IUPAC Recommendations; RSC Pub: Cambridge, UK, 2007. ISBN 978-0-85404-433-7.


No comments:

Post a Comment

periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...