Tuesday, May 22, 2018

inorganic chemistry - Why does Si2H4 readily polymerize at RTP but ethene does not (requires catalyst)?


In the case of both Silicon and Oxygen, the double bond is less stable than two single bonds. Consequently, surely both should polymerize, why don't they? What accounts for the difference between Carbon and Silicon in this context?




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...