Monday, April 30, 2018

equilibrium - Why is the Haber process carried out at such high temperatures?


On a large scale, ammonia is prepared via the Haber process:


NX2(g)+3HX2(g)2NHX3(g)ΔfH=46.1 kJmol1


The optimum conditions for the productions of ammonia are a pressure of 200 atm and a temperature of about 700 K.


The process obviously is exothermic and 700 K is, by no means, a low temperature. Shouldn't the temperature be much lower for optimum production of ammonia?



Answer



As others have pointed out, it is purely kinetics, but you may still wonder, why.


For a reaction to actually occur (in both directions) and thus for an equilibrium to be reached, you need to overcome the activation energy. In the case of the Haber-Bosch process, this involves breaking the highly stable NN triple bond. Even with the catalysts used, the energy required to break apart NX2 is still enormous. Therefore, a lower temperature may give a better yield of ammonia theoretically (i.e. based on equilibrium and Le Châtelier considerations) but the reaction speed would be a lot slower.


Even if you consider a batch-wise process of generating ammonia (which, as orthocresol points out, isn’t the case), it is more efficient to run two batches in half the time for two sets of 15 % than to run a single batch for twice the time to get an overall yield of maybe (note: This yield is a ballpark estimate) 25 % — with a batch size where 1 % yield is equivalent to 100 kg NHX3, two runs at higher temperature give 3 t NHX3 and one run at lower temperature 2.5 t NHX3 in the same time frame.


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