Friday, July 7, 2017

How to rationalise the difference in the melting points of acids and alcohols with inter molecular forces?


Acids: arachidic acid, palmitic acid, lauric acid, etc.
Alcohols: butan-1-ol, pentan-1-ol, etc.


The melting points of acids with $\ce{-COOH}$ at the end compared to melting points of alcohols, $\ce{-OH}$ at the end, is higher. I need to relate this to intermolecular forces. I was going to say that because of many more electrons in the acids, there are greater London dispersion forces and also more polarity (dipole dipole forces) because of the $\ce{COOH}$ at one end. Is this correct?




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