Monday, July 31, 2017

organic chemistry - How do people know HCN smells like almonds?


I was told by my chemistry teacher that HCN smells like almonds. She then went on to tell a story about how some of her students tried to play a prank on her by pouring almond extract down the drain to make her think that they had inadvertently created HCN gas. She said that she knew that it wasn't HCN because if she had smelled the almond scent, then she would have already been dead.


I never asked her, but how do people know HCN smells like almonds if they would die before they knew what it smells like?



Answer



The odour threshold for HCN is in fact quite a bit lower than the lethal toxicity threshold. Data for hydrogen cyanide can be found in many places, but here and here are a couple of good references. That subset of the human population that can detect bitter almonds do so at a threshold of 0.58 to 5ppm. The lethal exposure dose is upwards of 135ppm. That's a whole 100ppm range in which to detect and report the fragrant properties.


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