Sunday, November 4, 2018

stereochemistry - Is there a mathematical generalization for the number of isomers (structural and configurational) of a given compound?


The original question was:



How do I find the number of structural and configurational isomers of a given compound? is there any formula?



For a specific example, how would I find the number of structural and configurational isomers of a bromo compound $\ce{C5H9Br}$ formed by addition of $\ce{HBr}$ to 2-pentyne




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...