Friday, August 18, 2017

inorganic chemistry - What elements don't observe the octet rule?


Apart from hydrogen which forms a duet, which element's don't observe the octet rule?



Answer



Octet rule is more advisory than a rule; It's usually obeyed by the main group elements. Exception are paramagnetic compounds (obvious reason); first for elements in periodic system (He-configuration), 3-valent boron compounds; depending on counting system boron clusters (f.e. dodecaborane with 6-coordianted boron); transition metal complexes (these usually follow 18e rule, however there are plenty of examples with 14, 16 or even 20 electron complexes).


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