Friday, August 25, 2017

inorganic chemistry - Why is it considered acid rain with pH


I recently read in a book that rain is considered acid rain if the pH falls below 5.6. However a substance is acidic when the pH is below 7; so why is the boundary for acid rain 5.6?


I was thinking pH between 5.6-7 would be too diluted to have an effect on limestone and other materials, and that's why the pH has to be under 5.6. But I wasn't sure if this is true so I wanted to find out.



Answer



You are forgetting an important component of the air: carbon dioxide. When it dissolves in pure water (=rain water), it makes it acidic. It is not considered that harmful.


Acid rain has a negative connotation; it is mainly caused by anthropogenic activities. The low pH of acid rain is due to sulfur oxides and nitrogen oxides and it is indeed below 5.7.


IUPACs definition "Rain with pH values < about 5; commonly results from acids formed from pollutants. 'Pure' rain water equilibrated with atmospheric CO2 and naturally occurring acids in relatively clean air usually has a pH>5."



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