Saturday, February 4, 2017

organic chemistry - How is charge density a useful measure of polarising power and polarisability?


How do you use charge density ($Z/r$) as a measurement of polarising power and polarisability, and hence hard/soft acid character?


So far I've been looking at different polarising power and polarisability and how that affects a substance in whether it is a hard or soft acid/base, but I don't understand how charge density comes into play, and how we can use it to understand the characteristics.





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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...