Tuesday, November 6, 2018

inorganic chemistry - Do hydrogen halides (HX) form strong or weak acids?



I know that when dissolved in water, hydrogen halides ($\ce{H-X}$), become acids. I know that $\ce{HF}$ forms a weak acid, but can it be generalized that all $\ce{HX}$ acids do so?



Answer



No, it can’t be generalised. Amongst the haloacids, only $\ce{HF}$ is weak.


Acid strength can be determined by the stability of the conjugate base (for most acids, the conjugate base is what you get when you remove $\ce{H+}$ from the acid). In this case the conjugate bases are the halides.


As the size of the halide ion increases, the charge is dispersed over a larger volume, and thus the ion is more stable. In this manner, one can say that the order of acid strengths is $\ce{HF

$\ce{HCl, HBr, HI}$ are all strong acids. $\ce{HCl}$ has a $\mathrm{p}K_\text{a}$ of −7 (the smaller the $\mathrm{p}K_\text{a}$ is, the more acidic it is), $\ce{HBr}$ is approximately −9, and $\ce{HI}$ is also approx −9.


On the other hand, $\ce{HF}$ is 3.2. The $\ce{H-F}$ bond is pretty strong, so it has a smaller tendency to dissociate—making it a weak acid (not to say that it isn’t dangerous).


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