Thursday, July 19, 2018

molecular structure - Shape and polarity of the iodate ion


I am trying to figure out the shape of the iodate ion or $\ce{IO3^-}$. No matter how many times I draw it, I keep getting iodine in the centre, and 3 oxygen atoms surrounding it, 2 with single bonds, and 1 with a double bond. This would make it a trigonal planar shape. It would mean that it is not a "bent" shape.


I went to double check on the internet, and I am now confused. On Wikipedia it says it is in fact polar and a pyramidal shape.



Why does iodine have a pair of lone electrons in its shell? Why would it not combine with one of the oxygen atoms to make a double bond?




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...