Wednesday, July 18, 2018

inorganic chemistry - Dissociation rates: trans-effect rule in square planar complexes


In lecture, the trans-effect was described.


A ligand Lt with a higher trans-effect as L (cis to Lt) leads to a faster dissociation of ligand Ld (trans to Lt). I would expect that the attacking ligand B is needed to make a stronger bond as the leaving ligand Ld did.



In order to see if these assumptions are always valid in planar quadratic systems I've set up following problem according to the given trans-effect order:




CO has a stronger trans-effect as CHX3X and therefore the ligand trans to CO will be exchanged faster as trans to the CHX3X. But the leaving group IX would also have a higher trans-effect as ClX so I wouldn't expect a substitution in b). Are these statements correct?




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