Why are sigma bonds stronger than pi bonds?
Answer
The reason behind this is the orientation of the overlapped orbitals. Sigma bonds result from head-on(co-axial) overlapping while pi bonds are outcome of lateral(para-axial) overlapping. Here is a pictorial representation of ethene(sp2 hybridized C atoms) :
The greater the extent of overlapping, the higher the probability of finding the valence electrons in between the nuclei and hence the bond will be stronger & shorter.
In MOT, this can be explained using Overlap Integral. This is how Atkins depicts it :
In simple terms, after forming a sigma-bond (a pre-requisite for pi-bonds), the two atoms get locked along the inter-nuclear axis. As a result, the orbitals available for pi-bonding can only partially overlap, thus forming a weaker bond.
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