I'm trying to figure out if there is a direct relationship between these concepts. Strictly from the definitions, they appear to be different concepts in general. The more I think about it, however, the more I think they are very similar.
Let $X,Y$ be WSS random vectors. The covariance, $C_{XY}$, is given by $$C_{XY}=E\left[(X-\mu_x)(Y-\mu_y)^H\right]$$ where $H$ stands for the Hermitian of the vector.
Let $Z$ be a WSS random vector. The autocorrelation function, $R_{XX}$, is given by $$R_{ZZ}(\tau)=E\left[\left(Z(n)-\mu_z\right)\left(Z(n+\tau)-\mu_z\right)^H\right]$$
Edit Note There is a correction to this definition as applied to signal-processing, see Matt's Answer below.
The covariance does not involve a concept of time, it assumes each element of the random vector is a different realization of some random generator. The autocorrelation assumes a random vector is the time evolution of some initial random generator. Yet in the end, they are both the same mathematical entity, a sequence of numbers. If you let $X=Y=Z$, then it appears $$C_{XY}=R_{ZZ}$$ Is there something more subtle that I am missing?
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