Sunday, April 23, 2017

reaction mechanism - CH4 + O2 => CO2 + 2H2, what's wrong with it?


It says in my textbook that:


CHX4+2OX2COX2+2HX2O


which seems like a displacement reaction to me. Shouldn't the reaction be:


CHX4+OX2COX2+2HX2


since 4H are displaced by OX2 (becoming 2HX2), which makes the reaction balanced?


Why is the reaction CHX4+OX2COX2+HX2O, which is further balanced as my textbook says?




Answer



The reaction as you state it is correct only if there will react only one molecule of oxygen. But the reaction describes burning of methane which is supposed to be in the presence of excess of oxygen. Then not only methane is burnt, but also the arised hydrogen.


So in "first" step:


CHX4+OX2COX2+2HX2


but then the hydrogen will be also combusted in reaction :


2HX2+OX22HX2O


so the overall reaction will be:


CHX4+2OX2COX2+2HX2O


As was pointed out in the others answers the real mechanism of a methane combustion at a low oxygen pressure is more complicated:


49th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition, 4-7 January 2011, Orlando, Florida



49th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition, 4-7 January 2011, Orlando, Florida, http://enu.kz/repository/2011/AIAA-2011-94.pdf


another: COMBUSTION AND FLAME 120:160–172 (2000) Intermediate Species Profiles in Low-Pressure Methane/Oxygen Flames Inhibited by 2-H Heptafluoropropane: Comparison of Experimental Data with Kinetic Modeling, http://www.nist.gov/el/fire_research/upload/Williams-Intermediate-Species-profiles-in-Low-pressure-Methaneoxygen-Flames-inhibited-by-2-heptafluoropropane.pdf


No comments:

Post a Comment

periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, MgX2+ is closest in radius to LiX+. Is this true, and if so, why would a whole larger shell ($\ce{...