Friday, September 8, 2017

inorganic chemistry - Why chlorine acts as a strong field ligand in tetrachloridoplatinate(II)?


In most of the cases I have learnted, halogens act as a weak field ligand. However, I recently learned somewhere on the web that the strength of a ligand also depends upon the size of the atom. A classic example is tetrachloridoplatinate(II): $\ce{[Pt(Cl)4]^2-}$.


Why is it so, and how can I predict the hybridization correctly in such exceptions, if I come across them for the first time?




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...