Thursday, September 28, 2017

thermodynamics - Why do we use external pressure to find force exerted by gas on a piston in a closed vessel during its expansion?


I was reading a book in which i got confused due to this. A gas is in a vessel covered by a friction-less piston. Gas pressure is more than outer atmospheric pressure (which is constant) due to which it expands. Since it expands and move the piston outward, it does work on it which is calculated by force times displacement. In finding force we use Force = Pressure times Cross section area of piston. In finding this force to calculate work why are we using Pressure on piston by atmosphere and its weight and not pressure exerted by gas. Why? Can you also tell how the correct work done by gas can be calculated. Thanks.




No comments:

Post a Comment

periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...