Sunday, May 21, 2017

physical chemistry - Why does the Gibbs free energy only correspond to non-expansion work?


It has been defined as the energy available for work other than expansion work. Why can't it be used for expansion work





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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...