I recently looked up hydrogen sulfate ($\ce{HSO4-}$) to see how it's put together, and found this image of methyl hydrogen sulfate:
I'd assume that hydrogen sulfate looks the same, but without the methyl group attached. However I'm confused, how can it be constructed like that? This shows the sulfur having a total of 12 valence electrons, but shouldn't the maximum be 8?
I might be asking something that'll be obvious to me later on in chemistry, but this (and other groups that act as atoms) appear early on. I probably don't need to know it yet but I'd prefer to know how it works if I can as opposed to just accepting it.
Answer
I think it's time for you to know about Octet Expansion rule. The molecules that expand their octet are known as Hypervalent Molecules.
Normally, atoms in group 2 have 8 electrons and can thus form 4 bonds. This is mainly because they have s and p orbitals. However, in elements of group 3, they have extra orbitals called d orbitals that can be used to form more bonds. when forming extra bonds, the atom promotes electrons into the d orbitals and allows the atom to from more than 4 bonds.
Same thing happens in the case of sulfur. Sulfur belongs to 3rd period and therefore it has a vacant 3d orbital and thus can accommodate more than 8 electrons in its valence cell.
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