Wednesday, September 12, 2018

bond - Why is hydrogen sulfate put together as it is?


I recently looked up hydrogen sulfate ($\ce{HSO4-}$) to see how it's put together, and found this image of methyl hydrogen sulfate:


lewis structure of methylsulfate


I'd assume that hydrogen sulfate looks the same, but without the methyl group attached. However I'm confused, how can it be constructed like that? This shows the sulfur having a total of 12 valence electrons, but shouldn't the maximum be 8?


I might be asking something that'll be obvious to me later on in chemistry, but this (and other groups that act as atoms) appear early on. I probably don't need to know it yet but I'd prefer to know how it works if I can as opposed to just accepting it.



Answer



I think it's time for you to know about Octet Expansion rule. The molecules that expand their octet are known as Hypervalent Molecules.




Normally, atoms in group 2 have 8 electrons and can thus form 4 bonds. This is mainly because they have s and p orbitals. However, in elements of group 3, they have extra orbitals called d orbitals that can be used to form more bonds. when forming extra bonds, the atom promotes electrons into the d orbitals and allows the atom to from more than 4 bonds.



Same thing happens in the case of sulfur. Sulfur belongs to 3rd period and therefore it has a vacant 3d orbital and thus can accommodate more than 8 electrons in its valence cell.


No comments:

Post a Comment

periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, $\ce{Mg^2+}$ is closest in radius to $\ce{Li+}$. Is this true, and if so, why would a whole larger shell ($\ce{...