I'm interested in the second order reaction A+B⟶P. Mass action kinetics is assumed.
Let [A]0=a and [B]0=b, then [A]=a−x and [B]=b−x. The rate law becomes
−dxdt=−k([A]0−x)([B]0−x)
Why is the right-hand side of the differential equation negative? Shouldn't it just be the left side when we look at the decrease of the reactant A? Or is it because x is equal to the concentration of P?
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