Monday, November 6, 2017

kinetics - Second order reaction with two reactants



I'm interested in the second order reaction A+BP. Mass action kinetics is assumed.



Let [A]0=a and [B]0=b, then [A]=ax and [B]=bx. The rate law becomes


dxdt=k([A]0x)([B]0x)



Why is the right-hand side of the differential equation negative? Shouldn't it just be the left side when we look at the decrease of the reactant A? Or is it because x is equal to the concentration of P?




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