Sunday, November 5, 2017

coordination compounds - How do you determine the hybridisation state of a coordinate complex?


If an exercise asks for the hybridisation state of a coordinate complex (ion in solution) consisting of a central cobalt atom surrounded by NHX3 ligands, and neither coordination number or complex ion is given, how do you decide which configuration will occur?


The answer is that in a solution this will form a [Co(NHX3)X6]X3X+ complex ion. I know that this means the hybridisation is d2sp3 but can't figure out how to get there since cobalt is found in different oxidation states.




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periodic trends - Comparing radii in lithium, beryllium, magnesium, aluminium and sodium ions

Apparently the of last four, MgX2+ is closest in radius to LiX+. Is this true, and if so, why would a whole larger shell ($\ce{...