Tuesday, March 21, 2017

bond - Why do molecular orbitals in solids merge to bands?


Why do molecular orbitals in solids merge to bands?


For example: In silicon every atom is sp3 hybridised, but when I merge two of these orbitals then it yields a bonding and an antibonding MO. When a third atom binds to one of the $\ce{Si}$ atoms in this configuration, then again we should get two MOs, separated by the same energy. This way we we don't get so called bands. How do the bands form?


I have tried wikipedia and other sites but they answer in brief.




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