Saturday, March 25, 2017

bond - Why are some molecules unable to absorb infrared radiation?


Methane $\ce{CH4}$ is symmetrical and non polar, and so is oxygen $\ce{O2}$. But $\ce{O2}$ doesn't absorb IR. Why is that? People say that if a molecule can change its polarity then it will absorb IR, but I don't understand how a molecule changes its polarity while absorbing IR.


Please try to keep your answer simple — I don't have a strong background in infrared spectroscopy.




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